(三甲硅烷)重氮甲烷 | 18107-18-1
中文名称:
(三甲硅烷)重氮甲烷
英文名称:
(diazomethyl)trimethylsilane
CAS No.:
18107-18-1
分子式:
C4 H1 0 N2 SI
分子量:
114.22
名称和标识符
MDL
MFCD00053946
InChIKey
ONDSBJMLAHVLMI-UHFFFAOYSA-N
Inchi
InChI=1S/C4H10N2Si/c1-7(2,3)4-6-5/h4H,1-3H3
SMILES
C[Si](C)(C)C=[N+]=[N-]
BRN
1902903
别名信息
- 中文别名 -
(三甲硅烷)重氮甲烷
(三甲基硅烷基)重氮甲烷
三甲基硅烷化重氮甲烷
(三甲基硅基)亚磷酸盐
(三甲基硅烷基)重氮甲烷, 0.6 M 己烷溶液
三甲硅基重氮甲烷
三甲基硅重氮甲烷
三甲基硅重氮甲烷,2.0M 己烷溶液
(三甲基硅烷基)重氮甲烷(2M正己烷溶液)
2.0M 己烷溶液
三甲基硅烷化重氮甲烷,2M己烷溶液
三甲基硅烷化重氮甲烷 (约10%的己烷溶液,约0.6mol/L)
(三甲基硅烷基)重氮甲烷, 2.0 M 己烷溶液, J&KSEAL瓶
三甲基硅烷化重氮甲烷(+4℃)
三甲基硅烷化重氮甲烷 5ML
三甲基硅重氮甲烷(约10%的正己烷溶液,约0.6MOL/L)
三甲硅基重氮甲烷乙醚溶液
(三甲硅烷)重氮甲烷,2M /正己烷
三甲基矽三坐甲烷
三甲基硅烷化重氮甲烷,2mol/L in Hexanes
- 英文别名 -
(trimethylsilyl)diazomethane solution
(Trimethylsilyl)diazomethane
(TRIMETHYLSILYL)DIAZOMETHANE (2 M solution in Hexane)
(TRIMETHYLSILYL)DIAZOMETHANE 2M n-hexane
(Trimethylsilyl)diazomethane, 2.0M solution in diethyl ether, SpcSeal
C4H10N2Si
Diazomethyl(trimethyl)silane
TMS-Diazomethane
(Diazomethyl)trimethylsilane
(Diazomethyl)trimethylsilane,2M in hexane
(Trimethylsilyl)diazomethane [2.0M solution in hexane]
(TriMethylsilyl)diazoMethane(2M in hexanes)
(TriMethylsilyl)diazoMethane, 2M solution in hexanes
(Trimethylsilyl)diazomethane,approx. 2.0M
(Trimethylsilyl)diazomethane,approx. 2M
diazomethyl-trimethyl-silane
Tmschn2
Trimethylsil
Trimethylsilyldiazomethane
TMS-Diazomethane (ca. 10% in Hexane, ca. 0.6mol/L)
(trimethylsilyl)diazomethanesolution
TMS-DIAZOMETHANE
(TRIMETHYLSILYL)DIAZOMETHANE
(DIAZOMETHYL)TRIMETHYLSILANE
(Trimethylsilyl)diazomethane, ca. 2.0M solution in hexanes, tech.
Trimethylsilyldiazomethane,10%inhexane
TRIMETHYLSILYLDIAZOMETHANE, 1.0M IN METHYLENE CHLORIDE
(Trimethylsilyl)diazomethane solution 2M
(diazomethyl)trimethylsilane
TMSCH2N2
Me3SiCHN2
trimethysilyldiazomethane
(trimethylsilyl)-diazomethane
UNII-QI98HQO8C4
diazomethyltrimethyl silane
FT-0657646
trimethyl-silyl diazomethane
trimethylsilyldiazo-methane
[(Z)-diazomethyl]-trimethylsilane
(diazomethyl)(trimethyl)silane
(diazomethyl)-trimethylsilane
TMS Diazomethane
T1146
Trimethysilyl diazomethane
EN300-74206
TrimethylsilyldiaZomethane, ca. 10% in Hexane, ca. 0.6mol/L
18107-18-1
TMSdiazomethane
Diazomethyltrimethylsilane
(trimethysilyl)diazomethane
[(E)-Diazomethyl]-trimethylsilane
AT38821
AT25589
TMS-CHN2
diazomethyltrimethyl-silane
(TRIMETHYLSILYL)DIAZOMETHANE, 10% IN HEXANE
trimethylsilyldiazo- methane
DTXSID8074653
trimethylsilyidiazomethane
s19225
diazomethyl trimethylsilane
DIAZO((TRIMETHYLSILYL))METHANE [HSDB]
A812587
MFCD00053946
Trimethlsilyl diazomethane
F8889-7517
diazomethyl(trimethyl)silane
AMY15608
HSDB 8011
Trimethylsilyldiazomethane, 2 M in diethyl ether
trimethylsilyldiazomethan
(trimethylsilyl) diazomethane
(trimethylsilyl)diazo-methane
QI98HQO8C4
diazo((trimethylsilyl))methane
(trimethyl-silyl)diazomethane
AKOS015833333
Silane, (diazomethyl)trimethyl-
trimethylsilyl diazomethane
Q1990988
TMS -diazomethane
trimethylsilyldiazo methane
Diazomethyl-trimethyl-silane
TMSD
(CH3)3SiCHN2
trimethylsilyl-diazomethane
Trimethylsilyldiazomethane, 2M in hexane
trimethyl silyl diazomethane
TMSdiazo methane
Trimethylsilyldiazomethane, 10% in hexane
物化性质
实验特性
LogP
1.24546
PSA
37.39000
折射率
1.4362
水溶性
Immiscible with water. Miscible with organic solvents.
沸点
96 °C
闪点
-23 ºC
溶解度
Sol most organic solvents; insol H2O.
颜色与性状
不确定
溶解性
溶于大多数有机溶剂。
敏感性
Moisture & Light Sensitive
密度
0.718
计算特性
精确分子量
114.06100
氢键供体数量
0
氢键受体数量
1
可旋转化学键数量
1
同位素质量
114.061
重原子数量
7
复杂度
96.7
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
1
共价键单元数量
1
疏水参数计算参考值(XlogP)
无
互变异构体数量
无
表面电荷
0
拓扑分子极性表面积
2A^2
安全信息
符号:
GHS02
GHS06
GHS08
WGK Germany
3
安全术语
3
安全说明
S9-S16-S29-S33-S36/37-S61-S62
包装等级
II
包装类别
II
风险术语
R11; R38; R48/20; R51/53; R62; R65
危险等级
3
危险品标志
F
T+
N
危险品运输编号
UN 1208 3/PG 2
危害声明
H225,H302,H304,H315,H330,H336,H361,H373
警示性声明
P210,P260,P281,P284,P301+P310,P310
提示语
危险
储存条件
0-10°C
PackingGroup
II
危险类别码
R11;R23;R38;R48/20;R51/53;R62;R65;R67
信号词
Danger
TSCA
Yes
HazardClass
3
FLUKA BRAND F CODES
10
海关数据
海关编码
2931900090
海关数据
中国海关编码:
2931900090
概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
相关文献
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Redox-responsive organometallic foldamers from ferrocene amino acid: Solid-phase synthesis, secondary structure and mixed-valence properties
Daniel Siebler,Christoph F?rster,Katja Heinze Dalton Trans. 2011 40 3558
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Systematic methodology for the development of biocatalytic hydrogen-borrowing cascades: application to the synthesis of chiral α-substituted carboxylic acids from α-substituted α,β-unsaturated aldehydes
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Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl diazomethane
Anukul Jana,Herbert W. Roesky,Carola Schulzke Dalton Trans. 2010 39 132
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Unraveling the reactivity of a cationic iminoborane: avenues to unusual boron cations
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参考资料
Reaxys RN
956593
Beilstein
1902903
上游
3-环丙基-1H-吡唑
BOC-4-氧代-L-脯氨酸甲酯
2-溴苯并[d]噻唑-6-羧酸甲酯
1H-Pyrazole-4-carboxylic acid, 3-methoxy-1-methyl-, ethyl ester
环己基丙酮
3-溴邻氨基苯甲酸甲酯
(+/-)-2,2-二甲基-1.3-二氧戊环-4-羧酸甲酯
3,4-二甲氧基吡啶
环己基甲乙酮
METHYL 2-(5-BROMO-1H-INDOL-3-YL)ACETATE
2-(5-溴吡啶-3-基)乙酸甲酯
4-(N-叔丁氧基羰基氨基甲基)苯甲酸甲酯
1-Boc-吡咯烷-3-甲酸甲酯
甲基(+)-四氮-BOC-1-氮卡马西平-2-哌嗪羧酸盐
硬脂酰胺
N-[(1,1-二甲基乙氧基)羰基]-3,5-二碘-L-酪氨酸甲酯
(R)-1-N-Boc-2-吡咯烷甲腈
3-甲基-2-溴苯甲酸甲酯
3-氰基苯甲酸甲酯
2-((叔丁氧基羰基)氨基)-2-苯乙酸甲酯
Methyl 3-(2-fluorophenyl)propanoate
N-Boc-3-哌啶甲酸甲酯
(3-溴苯基)乙酸甲酯
双氯芬酸甲酯(双氯芬酸钠杂质) 标准品
3-叔丁基-1H-吡唑
R-甲基 1-boc-哌啶-2-羧酸
甲基(2Z,4E,6Z,8Z)-3,7-二甲基-9-(2,6,6-三甲基-1-环己烯基)壬-2,4,6,8-四烯酸酯
1,4-双(Boc)-2-哌嗪甲酸甲酯
6-吲哚烟酸甲酯
恩扎鲁胺杂质C
卡巴他赛
3-氟-4-硝基苯甲酸甲酯
Carbamic acid,(3-diazo-1-methyl-2-oxopropyl)-, 1,1-dimethylethyl ester, (R)- (9CI)
反-4,4'-二甲基-1,2-二苯乙烯
1-Boc-4-甲基-4-哌啶甲酸
1,3,4,6-四-氧-乙酰-β-D-吡啶甘露糖
吲唑-4-羧酸甲酯
甲基 4-溴-2-氟苯基乙酸酯
5-甲基噻吩-2-羧酸甲酯
2-氟-4-羟基苯甲酸甲酯
2-溴-3-糠酸甲酯
4-二甲基氨基苯乙烯
D-Phenylalanine,N-acetyl-, methyl ester
八乙烯基-T8-倍半硅氧烷
1-苄基-4-哌啶甲醛
Silane, (1-cyclohepten-1-yloxy)trimethyl-
4-磺酰基苯甲酸甲酯
N-Phenethylformamide
5-甲氧基-2-硝基苯甲酸甲酯
3-羟甲基吡唑
京尼平甙
2-氨基-5-甲氧基苯甲酸甲酯
2-氨基-4氟苯甲酸甲酯
反式-4-(2-丙炔)环己烷羧酸甲酯
甲基1,2 -二甲基-1H-1,3 -苯并咪唑-5 -甲酸叔丁酯
Carbamic acid, (2-phenylethyl)-, methyl ester
4-((叔丁氧基羰基)氨基)烟酸甲酯
N-[(苯基甲氧基)羰基]-L-丙氨酸甲酯
3-溴-4-羟基苯甲酸甲酯,98
4-溴吡啶-2-甲酸甲酯
2-苄基丙烯酸甲酯
4-[(4-甲基哌嗪-1-基)甲基]苯甲酸甲酯
1,2,4-哌嗪三羧酸,4-(1,1-二甲基乙基)2-甲基1-(苯基甲基)酯,(2S)-
N-BOC-甘氨酸甲基
4-氨基-1,4-哌啶二羧酸 1-(1,1-二甲基乙基) 4-甲酯
5-氯吡嗪-2-羧酸甲酯
3-溴-5-氟苯甲酸甲酯
4-碘苯基丙酸甲酯
2-环己基环氧乙烷
甲基4-氟苯基乙酸
5-氨基吡啶-3-甲酸甲酯
3-氨基吡啶-2-羧酸甲酯
N-乙酰-L-苯丙氨酸甲酯
5-溴-2-(2-甲基-2H-四唑-5-基)-吡啶
(2S,4E)-5-氯-2-异丙基戊-4-烯酸甲酯
2-氟-4-硝基苯甲酸甲酯
5-氟-2-硝基苯甲酸甲酯
7-氮杂吲哚-2-羧酸甲酯
4'-羟基-4-联苯基羧酸甲酯
2-溴-5-氯苯酚
(R)-1-Boc-3-羧基吡咯烷甲酯
3-氟-4-硝基苯甲醚
1-氨基-1-环己基甲酸甲酯
3-溴-5-甲基苯甲酸甲酯
Methyl 3-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)propanoate
2-氨基-5-溴烟酸甲酯
2-甲基溴代苯乙酮
5-苯基异噁唑-3-羧酸甲酯
Boc-L-苯丙氨酸甲酯
methyl 2-(acetylamino)-3-phenylprop-2-enoate
4-(4-乙基苯)丁酸
环己基乙醛
5-氨基-2-氟苯甲酸甲酯
5-溴-2-氟苯甲酸甲酯
2-溴苯乙酸甲酯
2-(1-甲基-1H-吲哚-3-基)乙酸甲酯
3-溴异烟酸甲酯
Boc-L-脯氨酸甲酯
N-Boc-氮杂环丁烷-3-甲酸甲酯
Z-L-天冬氨酸 BETA叔丁酯 ALPHA甲酯
间氟苯乙酸甲酯
2-氨基-4-噻唑乙酸甲酯
2-溴-4-氟苯甲酸甲酯
N-Boc-4-硝基-L-苯基丙氨酸甲酯
2-溴-6-氯苯甲酸甲酯
2'-O-methyl-honokiol
5-甲氧基喹啉
2-溴-5-氟苯甲酸甲酯
苯甲酸,4-(氯磺酰基)-,甲酯
(S)-(-)-2-氯丙酸甲酯
(4-甲酰基苯氧基)乙酸甲酯
N-Boc-3,4-去氢-L-脯氨酸
(R)-(+)-2-氯丙酸甲酯
2-丁醇,3-氨基-1,1-二甲氧基-3-甲基-
5-溴-6-氯烟酸甲酯
7-氮杂吲哚-3-羧酸甲酯
甲基酮环己酯
3-溴-4-氟苯甲酸甲酯
4H-噻唑[3,2-B]吡咯-5-甲酸甲酯
西替利嗪甲酯
2.6-二氟-3-硝基苯甲酸甲酯
3-氨基-6-氯吡啶甲酸甲酯
3-氟吡啶-2-羧酸甲酯
2-溴-1-(4-溴-2-氟苯基)乙酮
3-去甲基硫代秋水仙碱
2-溴-4-甲基苯甲酸甲酯
6-氯-3-甲基-2-吡啶羧酸甲酯
METHYL 2-BROMO-5-FLUOROISONICOTINATE
2-硝基-3-羟基苯甲酸甲酯
N-Boc-L-烯丙基甘氨酸甲酯
3(2H)-氧-4氟苯并呋喃
BOC-D-丝氨酸甲酯
2-溴-6-甲基苯甲酸甲酯
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