粘酸 | 526-99-8
中文名称:
粘酸
英文名称:
Galactaric acid
CAS No.:
526-99-8
分子式:
C6 H1 0 O8
分子量:
210.1388
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:粘酸结构式
名称和标识符
MDL
MFCD00004239
InChIKey
DSLZVSRJTYRBFB-DUHBMQHGSA-N
Inchi
1S/C6H10O8/c7-1(3(9)5(11)12)2(8)4(10)6(13)14/h1-4,7-10H,(H,11,12)(H,13,14)/t1-,2+,3+,4-
SMILES
O([H])[C@@]([H])([C@@]([H])(C(=O)O[H])O[H])[C@@]([H])([C@]([H])(C(=O)O[H])O[H])O[H]
BRN
1728117
别名信息
- 中文别名 -
粘酸
粘液酸
黏酸
Mucic Acid 黏酸
半乳糖二酸
黏液酸
四羟己二酸
四氢-3,4-二羟呋喃-2,5-二甲酸
粘酸,黏液酸,半乳糖二酸
四羟基己二酸
糖乳酸
- 英文别名 -
(2R,3S,4R,5S)-2,3,4,5-Tetrahydroxyhexanedioic acid
Galactaric acid~Tetrahydroxyadipic acid
Galactaric acid
MUCIC ACID
MUCIC ACID(RG)
2,3,4,5-Tetrahydroxyadipic Acid
D-Mucic acid
Galactarsaeure
GALACTERIC ACID
galactosaccharic acid
GALATARIC ACID
L-Mucic acid
Mucic
Schleimsaure
MTPA
Tetrahydroxyhexanedioic acid
MUCICACID
Saccharolactic acid
D-Galactaric acid
D-galactarate
galactarate
meso-galactaric acid
Tetrahydroxyadipic acid
E149J5OTIF
Schleimsaure [German]
2R,3S,4R,5S-tetrahydroxy-hexanedioic acid
DSSTox_RID_82936
DSSTox_CID_28666
DSSTox_GSID_48740
hexaric acid
Galactaric Acid
Galactaric-acid-
KBio2_000589
BCP29834
NS00010082
SpecPlus_000412
DSLZVSRJTYRBFB-UHFFFAOYSA-N
NCI60_000682
KBio2_003157
A9C2B0B4-D17A-489A-A900-65FFAE0F00B6
FT-0670273
Obetrol
SCHEMBL5497
SDCCGMLS-0066970.P001
WLN: QVYQYQYQYQVQ
d-Galactaric acid #
SB45456
SPECTRUM1501211
Spectrum5_000600
FT-0626588
SR-05000002451
2,3,4,5-Tetrahydroxyhexanedioic acid
CCG-38868
AKOS024386337
LS-13158
SR-05000002451-1
Glucaric acid
Saccharic acid
FT-0690188
NSC8127
Spectrum4_001910
Spectrum_000129
SPBio_001347
SY061881
Galactaric acid, D-
Spectrum2_001454
KBioGR_002506
80876-58-0
DivK1c_006508
KBio1_001452
NCGC00096080-01
NSC-8127
KBio2_005725
KBioSS_000589
物化性质
实验特性
LogP
-3.40080
PSA
155.52000
Merck
4331
折射率
1.5800 (estimate)
水溶性
Soluble in water.
沸点
269.65°C (rough estimate)
熔点
220-225 °C (dec.) (lit.)
闪点
431.2ºC
溶解度
3.3g/l soluble
颜色与性状
白色结晶性粉末
溶解性
溶于300份冷水,60份沸水和碱溶液。几乎不溶于乙醇和乙醚
密度
1.5274 (rough estimate)
计算特性
精确分子量
210.03800
氢键供体数量
6
氢键受体数量
8
可旋转化学键数量
5
同位素质量
210.038
重原子数量
14
复杂度
202
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
4
确定化学键立构中心数量
0
不确定化学键立构中心数量
0
共价键单元数量
1
疏水参数计算参考值(XlogP)
-2.5
表面电荷
0
拓扑分子极性表面积
156
生产方法和用途
用途
用于生化研究。用作金属螯合剂,合成杂环化合物的中间体和凝结物硬化延迟剂。
生产方法
由半乳糖、半乳糖醇或半乳糖醛酸经硝酸氧化生成。
相关文献
1.
Production of 2,5-furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF): recent progress focusing on the chemical-catalytic routes
Muhammad Sajid,Xuebing Zhao,Dehua Liu Green Chem. 2018 20 5427
2.
Chiral and achiral linear coordination polymers from aldaric acids
Brendan F. Abrahams,Martin J. Grannas,Laura J. McCormick,Richard Robson,Peter J. Thistlethwaite CrystEngComm 2010 12 2885
3.
166. Studies in optical superposition. Part IX. 1-Menthyl esters of mucic and tetrahydroxyadipic [graphic omitted] acids
Robert W. Lapsley,John Robertson,T. S. Patterson J. Chem. Soc. 1940 862
4.
Interfacial assembly structures and nanotribological properties of saccharic acids
Hongyu Shi,Yuhong Liu,Qingdao Zeng,Yanlian Yang,Chen Wang,Xinchun Lu Phys. Chem. Chem. Phys. 2017 19 1236
5.
Synthesis of 2,5-furandicarboxylic acid dimethyl ester from galactaric acid via dimethyl carbonate chemistry
Giacomo Trapasso,Mattia Annatelli,Davide Dalla Torre,Fabio Aricò Green Chem. 2022 24 2766
6.
Development of a flow process for an easy and fast access to 2-pyrone derivatives
Grazia Isa C. Righetti,Francesca Tentori,Elisabetta Brenna,Cristian Gambarotti React. Chem. Eng. 2023 8 199
7.
Biorefinery of galacturonic acid using a biofuel cell as a reactor
Tomoe Nakagawa,Hayato Abe,Tomoko Gessei,Kouta Takeda,Kiyohiko Igarashi,Nobuhumi Nakamura React. Chem. Eng. 2022 7 2629
8.
Transition metal-catalyzed deoxydehydration: missing pieces of the puzzle
Friederike C. Jentoft Catal. Sci. Technol. 2022 12 6308
9.
747. The chemistry of quadrivalent germanium. Part VIII. Complexes of germanium with tartaric, lactic, and mucic acid
D. A. Everest,J. C. Harrison J. Chem. Soc. 1960 3752
10.
Vanadium(iv,v) complexes of d-saccharic and mucic acids in aqueous solution
ágnes D?rnyei,Eugenio Garribba,Tamás Jakusch,Péter Forgó,Giovanni Micera,Tamás Kiss Dalton Trans. 2004 1882
参考资料
Reaxys RN
1728117
Beilstein
3,581
960化工网为您提供粘酸专业化合物百科信息,包括中文名,英文名,分子式,分子量,以及该化合物的CasNo.:526-99-8,和相关理化性质;并提供了优质生产厂家信息包括厂家名称和联系方式等