D-( )-吡喃葡萄糖 | 59-23-4
中文名称:
D-( )-吡喃葡萄糖
英文名称:
D-Galactose
CAS No.:
59-23-4
分子式:
C6 H1 2 O6
分子量:
180.1559
名称和标识符
MDL
MFCD00151230
InChIKey
WQZGKKKJIJFFOK-SVZMEOIVSA-N
Inchi
1S/C6H12O6/c7-1-2-3(8)4(9)5(10)6(11)12-2/h2-11H,1H2/t2-,3+,4+,5-,6?/m1/s1
SMILES
O1C([H])([C@@]([H])([C@]([H])([C@]([H])([C@@]1([H])C([H])([H])O[H])O[H])O[H])O[H])O[H]
BRN
1724619
别名信息
- 中文别名 -
D-( )-吡喃葡萄糖
D-半乳糖
D-吡喃葡萄糖
D-( )-半乳糖
D(+)-半乳糖
无水 D-(+)-半乳糖
D-( )-吡喃葡萄糖 D-半乳糖
D(-)-半乳糖
D-(+)-Galactose Anhydrous 无水 D-(+)-半乳糖
D(+)Galactose D-(+)半乳糖
D(+)半乳糖
D-(+)-半乳糖
D-(+)-半乳糖 (RG)
D(+)-半乳糖 标准品
D-(+)-半乳糖, 无水
D-(+)-半乳糖,水解乳糖
D-(+)-吡喃葡萄糖
D--半乳糖
D半乳糖
D-半乳糖 标准品
D-半乳糖(植物)
D-半乳糖,AR
D-吡喃半乳糖
L-阿拉伯糖
半乳糖
半乳糖 EP标准品
吡喃葡萄糖 USP标准品
a-D-吡喃半乳糖
D(+)-半乳糖(D-半乳糖,D-吡喃葡萄糖,D-(+)-吡喃葡萄糖,水解乳糖,分解乳糖)
D(+)-半乳糖、D-吡喃葡萄糖
D-半乳糖,D-Galactose,分析标准品
半乳糖(D-半乳糖)
分解乳糖
分解乳糖,D-吡喃葡萄糖,D-(+)-半乳糖
口服葡萄糖
水解乳糖
D-水解乳糖
D-半乳糖(分析标准品)
+-半乳糖
+-吡喃葡萄糖,水解乳糖,分解乳糖
D-半乳糖,D-吡喃葡萄糖,D-
半乳糖(标定对照品)
- 英文别名 -
D-Galactose
galactose, pure
D-(+)-Galactose
D(+)Galactose anhydrous
alpha-Galactose(D)
Gal
Galactose
D-(+)-Galactose Anhydrous
GALACTOSE, D-(+)-(RG) PrintBack
D (+) GALACTOSE
D-Glactose
(+)-galactose
brain sugar
Cerebrose
D(+)-Glactose
Dextrogalactose
d-galactos
galactos
Lactoglucose
MaltaseHydrate
Galactose,D- (8CI)
D-Galactopyranose
Galactopyranose
Galactopyranoside
D-Galactopyranoside
D-Gal
SMR000857326
Echocon
Echovist
dl-Galactose
D-Galactose (9CI)
Galactose, D- (8CI)
DSSTox_CID_3088
Epitope ID:141794
Shu 450
Shu 454
DSSTox_RID_76869
DSSTox_GSID_23088
MLS001335983
MLS
D-Galactose, CP
D-(+)-Galactose D(+)-Galactose, extra pure, Ph Ned, Ph Helv
Galactose (200 mg)
D-Galactose, D-(+)-Galactose
D(+)-GALACTOSE ANHYDROUS CELL CULTURE*TE STED
D(+)-GALACTOSE, FOR BIOTECHNOLOGICAL PUR POSES
D-(+)-GALACTOSE, BIOTECH
(+)-Galactose
物化性质
实验特性
LogP
-3.22140
PSA
110.38000
Merck
4335
折射率
80 ° (C=10, H2O)
水溶性
Soluble in water.
沸点
527.1℃ at 760 mmHg
熔点
168-170 °C (lit.)
蒸气压
0.0±3.1 mmHg at 25°C
闪点
202.2℃
溶解度
H2O: 100 mg/mL
颜色与性状
白色结晶或粉末。无气味。微有甜味。
PH值
4.5-6.0 (H2O)Aqueous solution
溶解性
易溶于水,溶于吡啶,微溶于乙醇和甘油。
敏感性
对湿度敏感
酸度系数(pKa)
pK1:12.35 (25°C)
比旋光度
+77.0° - +84.0° (c=4, H2O)
密度
1.500(lit.)
计算特性
精确分子量
180.06300
氢键供体数量
5
氢键受体数量
6
可旋转化学键数量
1
同位素质量
180.063388
重原子数量
12
复杂度
151
同位素原子数量
0
确定原子立构中心数量
4
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
0
共价键单元数量
1
疏水参数计算参考值(XlogP)
-2.6
表面电荷
0
拓扑分子极性表面积
110
分子量
180.16
海关数据
海关编码
29400090
海关数据
中国海关编码:
29400090
生产方法和用途
方法
HPLC
HPLC(Differential)
用途
用于有机合成,医药上用于测定肝功能
营养药。
肝功能试验,有机合成,生物培养。
相关文献
1.
Chlorogenic acid combined with epigallocatechin-3-gallate mitigates d-galactose-induced gut aging in mice
Ran Wei,Zhucheng Su,Gerardo G. Mackenzie Food Funct. 2023 14 2684
2.
Non-stoichiometric formation of formic and levulinic acids from the hydrolysis of biomass derived hexose carbohydrates
T. Flannelly,M. Lopes,L. Kupiainen,S. Dooley,J. J. Leahy RSC Adv. 2016 6 5797
3.
Carbohydrate phosphates. Part I. Synthesis of derivatives of some aldehydo-sugar phosphates
J. L. Barclay,A. B. Foster,W. G. Overend J. Chem. Soc. 1955 2505
4.
165. Studies on agar-agar. Part III. Isolation of hepta-acetyl dl-galactose from 3 : 6-anhydro-β-methyl-d-galactoside
T. L. Cottrell,E. G. V. Percival J. Chem. Soc. 1942 749
5.
Controlled aggregation of adenine by sugars: physicochemical studies, molecular modelling simulations of sugar–aromatic CH–π stacking interactions, and biological significance
Marc Maresca,Adel Derghal,Céline Carravagna,Séverine Dudin,Jacques Fantini Phys. Chem. Chem. Phys. 2008 10 2792
6.
Organic chemistry
F. S. Spring,L. N. Owen,E. R. H. Jones,H. T. Openshaw Annu. Rep. Prog. Chem. 1943 40 98
7.
Characterizing serum metabolic alterations of Alzheimer's disease and intervention of Shengmai-San by ultra-performance liquid chromatography/electrospray ionization quadruple time-of-flight mass spectrometry
Shengwen Lu,Ying Han,Hang Chu,Ling Kong,Aihua Zhang,Guangli Yan,Hui Sun,Ping Wang,Xijun Wang Food Funct. 2017 8 1660
8.
Recent progress in the chemistry of the pectic materials and plant gums
E. L. Hirst J. Chem. Soc. 1942 70
9.
The Occurrence and significance of the pentose sugars in nature, and their relationship to the hexoses
E. L. Hirst J. Chem. Soc. 1949 522
10.
Deoxy-sugars. Part XXV. Structure and reactivity of anhydro-sugars. Part II. Derivatives of 3 : 6-anhydro-D-mannose, 3 : 6-anhydro-2-deoxy-D-galactose, and 3 : 6-anhydro-2-deoxy-D-glucose
A. B. Foster,W. G. Overend,M. Stacey,G. Vaughan J. Chem. Soc. 1954 3367
参考资料
Reaxys RN
1724619
Beilstein
1724619
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