三苯基氯甲烷 | 76-83-5
中文名称:
三苯基氯甲烷
英文名称:
(chlorodiphenylmethyl)benzene
CAS No.:
76-83-5
分子式:
C1 9 H1 5 CL
分子量:
278.7754
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:三苯基氯甲烷结构式
名称和标识符
MDL
MFCD00000813
InChIKey
JBWKIWSBJXDJDT-UHFFFAOYSA-N
Inchi
1S/C19H15Cl/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
SMILES
C1=CC=C(C=C1)C(C2=CC=CC=C2)(C3=CC=CC=C3)Cl
BRN
397363
别名信息
- 中文别名 -
三苯基氯甲烷
氯代三苯甲烷
氯三苯甲烷
三苯基甲基氯
氯化三苯基甲烷
氯化三苯甲基
Trityl Chloride 三苯基氯甲烷
三苯甲基氯
- 英文别名 -
(Chloromethanetriyl)tribenzene
alpha-chlorotriphenylmethane
BENZENE, 1,1',1''-(CHLOROMETHYLIDYNE)TRIS-
CHLOROTRIPHENYLMETHANE
PH3C-CL
TRIPHENYLCHLORMETHANE
TRIPHENYLCHLOROMETHANE
TRITY CHLORIDE
TRITYL CHLORIDE
TRT-CL
[Chloro(diphenyl)methyl]benzene
1,1',1''-(chloromethylidyne)tris-benzen
1,1',1''(-Chloromethylidyne)trisben-zene
chlorotriphenyl-methan
Methane, chlorotriphenyl-
D-(-)-p-Hydroxyphenylglycine Dane Salt(M.K.)
syn. Nae Chlorotriphenylmethane
Trityl chloride (Triphenylchloromethane)
Triphenylmethyl chloride (Trityl chloride)
TryTylchloride
(Chlorodiphenylmethyl)benzene
Triphenyl chloeomethane
Triphenylmethyl chloride
[chloro-di(phenyl)methyl]benzene
1,1',1"-(chloromethanetriyl)tribenzene
ChlorotriphenylMethane
Triphenylchloromethane
物化性质
实验特性
LogP
5.21730
PSA
0.00000
折射率
1.6281 (estimate)
水溶性
Insoluble in water. Soluble in chloroform, hexane, benzene, ether, acetone and tetrahydrofuran.
沸点
230-235 °C/20 mmHg(lit.)
熔点
109-112 °C (lit.) 109-113 °C
闪点
230-235°C/20mm
溶解度
chloroform: 0.1 g/mL, clear
颜色与性状
白色晶体
溶解性
易溶于苯和二硫化碳、氯仿、四氯化碳,微溶于醇和醚,不溶于水。
敏感性
Lachrymatory
密度
1.1088 (rough estimate)
计算特性
精确分子量
278.08600
氢键供体数量
0
氢键受体数量
0
可旋转化学键数量
3
同位素质量
278.086228
重原子数量
20
复杂度
235
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
0
共价键单元数量
1
疏水参数计算参考值(XlogP)
无
互变异构体数量
无
表面电荷
0
拓扑分子极性表面积
0
海关数据
海关编码
29036990
海关数据
中国海关编码:
2903999090
概述:
2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
Summary:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
相关文献
1.
61. Condensation of chlorotriphenylmethane with ortho-disubstituted benzenes. Further evidence on the systematic difference of activation of ortho- and para-directing groups
Gabriel Chuchani J. Chem. Soc. 1960 325
2.
238. Mechanism of substitution at a saturated carbon atom. Part LVI. Kinetics of the reaction of triphenylmethyl chloride with methyl alcohol in benzene
E. D. Hughes,C. K. Ingold,S. F. Mok,Y. Pocker J. Chem. Soc. 1957 1238
3.
Chemical routes to discharging graphenides
Stephen A. Hodge,David J. Buckley,Hin Chun Yau,Neal T. Skipper,Christopher A. Howard,Milo S. P. Shaffer Nanoscale 2017 9 3150
4.
TsOH-catalyzed acyl migration reaction of the Bz-group: innovative assembly of various building blocks for the synthesis of saccharides
Xing-Yong Liang,An-Lin Liu,Hua-Jun Shawn Fan,Lei Wang,Zhi-Ning Xu,Xin-Gang Ding,Bo-Shun Huang Org. Biomol. Chem. 2023 21 1537
5.
Inclusion of triphenylmethane derivatives by crown and linear O-containing molecules?:? selective interactions and crystal structures
Marina S. Fonari,Yurii A. Simonov,Wen-Jwu Wang,Shang-Wei Tang,Eduard V. Ganin CrystEngComm 2009 11 94
6.
One pot synthesis of 1,2,4,5-tetrasubstituted-imidazoles catalyzed by trityl chloride in neutral media
Ahmad Reza Moosavi-Zare,Zhila Asgari,Abdolkarim Zare,Mohammad Ali Zolfigol,Mohsen Shekouhy RSC Adv. 2014 4 60636
7.
Towards poly(ester) nanoparticles: recent advances in the synthesis of functional poly(ester)s by ring-opening polymerization
Ryan J. Pounder,Andrew P. Dove Polym. Chem. 2010 1 260
8.
Cascade reaction of β,γ-unsaturated α-ketoesters with phenols in trityl chloride/TFA system. Highly selective synthesis of 4-aryl-2H-chromenes and their applications
Yan-Chao Wu,Hui-Jing Li,Li Liu,Zhe Liu,Dong Wang,Yong-Jun Chen Org. Biomol. Chem. 2011 9 2868
9.
Carbocation catalysis in confined space: activation of trityl chloride inside the hexameric resorcinarene capsule
Margherita De Rosa,Stefania Gambaro,Annunziata Soriente,Paolo Della Sala,Veronica Iuliano,Carmen Talotta,Carmine Gaeta,Antonio Rescifina,Placido Neri Chem. Sci. 2022 13 8618
10.
The role of dynamic ligand exchange in the oxidation chemistry of cerium(iii)
Jerome R. Robinson,Yusen Qiao,Jun Gu,Patrick J. Carroll,Patrick J. Walsh,Eric J. Schelter Chem. Sci. 2016 7 4537
参考资料
Reaxys RN
397363
Beilstein
397363
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上游
氯化二甲基氨基偶氮苯
Tetrakis(4-bromophenyl)methane 四(4-溴苯基)甲烷
普拉格雷中间体 N-三苯甲基-4,5,6,7-四氢噻吩并[3,2-C]吡啶
5,6,7,7a-四氢-5-(三苯甲基)噻吩并[3,2-c]吡啶酮
Uridine,5-methyl-5'-O-(triphenylmethyl)-, 2',3'-dimethanesulfonate (9CI)
N-(三苯基甲基)-5-(4'-溴甲基联苯-2-基)四氮唑
N-(三苯基甲基)-5-(4'-甲基联苯-2-基)四氮唑
[2-丁基-4-氯-1-[(2'-(1-三苯甲基-1H-四氮唑-5-基)联苯-4-基)甲基)-1H-咪唑-5-基)甲醇
头孢地尼侧链酸
反式-4-羟基-n-三苯基甲基-l-脯氨酸甲酯
Fmoc-O-三苯甲基-L-苏氨酸
Ethanol, 2-[2-[2-(triphenylmethoxy)ethoxy]ethoxy]-
small>-丝氨酸甲酯
三苯甲基坎地沙坦
(Z)-2-(2-氨基噻唑-4-基)-2-三苯甲氧亚氨基乙酸(2-巯基苯并噻唑)酯
5-(2-溴苯基)-1-三苯甲基-1H-四氮唑
三苯甲基坎地沙坦西来替昔酯
N-BOC-S-三苯甲基-L-半胱氨酸
3-(三苯甲硫基)丙酸
(R)-2-乙酰胺基-3-(三苯甲基硫基)丙酸
1-三甲苯-(R)-3-甲基哌嗪
N-Boc-N'-三苯甲基-L-组氨酸
N(IM)-(三苯甲基)-L-组氨酸
9N-三苯甲基鸟嘌呤
1-三苯甲基-1H-咪唑-4-羧酸乙酯
Nα-Trityl-L-histidin
4,4',4'',4'''-Methanetetrayltetraaniline
4-Thiazoleacetic acid, a-(methoxyimino)-2-[(triphenylmethyl)amino]-,ethyl ester, (Z)- (9CI)
4-硝基苯基-6-O-三苯甲基-Α-D-吡喃葡萄糖苷
N-(P-甲苯磺酰基)吲哚-3 - 硼酸
1-(三苯基甲基)-1H-咪唑-2-甲醛
三苯甲基头孢地尼侧链酸
1-氯-3-o-三苯甲游基-2-丙醇
(S)-(-)-1-三苯甲基-2-氮丙啶羧酸甲酯
Methyl 1-trityl-1H-imidazole-4-carboxylate
N-三苯甲基硫脲
5-苯基-2-三苯基甲基四唑
N-三苯甲基-4-溴吡唑
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